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The following conclusions were drawn from the SAR studies of DCK and DCP analogs and derivatives: (1) A bi-ring system is a requirement, and a planar system is probably an essential feature for potent anti-HIV activity. Steric compression between DCK C-4 and C-5 substituents or phenyl substituents on the skeleton can reduce the overall planarity and, thus, resonance of the system, which results in decreased or completely lost activity. (2) The stereochemistry at the 30 and 40 positions should be R-con gured, and an isovaleryl structural feature is essential on these positions. Camphanoyl moieties are the most potent substituents. (3) Methyl or other aliphatic substitutions on the DCK C-3, C-4, and C-5 are favorable for anti-HIV activity against the non-drug-resistant strain, whereas aromatic substituents and 6-substitution are not. The DCK C-3 can tolerate polar but not charged or electron withdrawing substituents. (4) The bioisosteric isomers, thioDCK, and DCK lactam retain activity. (5) The positional isomer, DCP, is even more promising because most DCP analogs are active against a multiple RT inhibitor resistant strain, whereas most DCK derivatives are ineffective against this RT inhibiter resistant strain. An appropriate alkyl substituent at position 2 is critical for the anti-HIV activity of DCP analogs against both viral strains. In addition, most 2-substituted DCP analogs are less toxic to the cells compared with DCP.43,46 9.2.5 Mechanism of Action

It is then subjected to chemical leaching followed by a separation of the liquids and solids, followed by concentration/puri cation and nal product recovery The normal choice ( 80% of all US ores) for chemical leaching is acid leaching with sulfuric acid (due to its low cost and great availability) For the ores that have high carbonate content, an alkaline leach with Na2CO3 is used to prevent high acid concentration The problem in acid leaching is that only U(VI) dissolves in H2SO4 Any U(IV) present must be oxidized to U(VI) prior to leaching.

The biogas is then cleaned and ltered to remove chemical compounds The gas is used in more ef cient power generation systems called combined cycles, which combine gas turbines and steam turbines to produce electricity The ef ciency of these systems can reach 60% Gasi cation systems may also be coupled with fuel cell systems using a reformer to produce hydrogen and then convert hydrogen gas to electricity (and heat) using an electrochemical process Interest in biomass gasi cation increased substantially in the 1970s because of uncertainties in petroleum supplies Most development activities were concentrated on small-scale systems Low-energy gasi ers are now commercially available, and dozens of small-scale facilities are in operation..

The chemical steps can be summarized as FeS2 , Fe H2 SO4 Fe2 H2 SO2 ! 4 2Fe2 MnO2 4H 2Fe3 Mn2 2H2 O ! or 6Fe2 NaClO3 6H 6Fe3 NaCl 3H2 O ! leading to UO2 2Fe3 UO2 2Fe2 ! 2 UO3 H2 SO4 UO2 SO2 H2 O ! 2 4 UO2 2SO2 ( UO2 (SO4 )2 2 ( UO2 (SO4 )3 4 ) ) 2 4 The nal product thus appears in three chemical forms, UO2 , [UO2(SO4)2]22, and 2 [UO2(SO4)3]42 In alkaline leaching of high carbonate materials, one takes advantage of the unique solubility of [UO2(CO3)3]42 One begins with nely divided material and must also deal with the oxidation of any U(IV) that is present The basic reaction (pun intended) is UO2 (oxidant, Ox) 3CO2 UO2 (CO3 )3 4 Ox2 ! 3.

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